K. Hirsch, V. Zamudio-Bayer, A. Langenberg, M. Niemeyer, B. Langbehn, T. Möller, A. Terasaki, B. v. Issendorff, J. T. Lau
The magnetic moment of a single impurity atom in a finite free electron gas is studied in a combined x-ray magnetic circular dichroism spectroscopy and density functional theory study of size-selected free chromium-doped gold clusters. The observed size-dependence of the local magnetic moment can essentially be understood in terms of the Anderson impurity model. Electronic shell closure in the host metal minimizes the interaction of localized impurity states with the confined free electron gas and preserves the full magnetic moment of $\unit[5]{\mu_B}$ in $\mathrm{CrAu}_{2}^{+}$ and $\mathrm{CrAu}_{6}^{+}$ clusters. Even for open-shell species, large local moments are observed that scale with the energy gap of the gold cluster. This indicates that an energy gap in the free electron gas generally stabilizes the local magnetic moment of the impurity.
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http://arxiv.org/abs/1304.7173
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