Rui-Ning Wang, Jorge H. Rodriguez, Wu-Ming Liu
Spin dependent transport has been investigated for an {\it open shell singlet} diiron-oxo cluster. Currents and magnetoresistances have been studied, as a function of spin state, within the non-equilibrium Green's function approach. The applied bias can be used for tuning the sign of the observed magnetoresistance. A colossal magnetoresistance ratio has been determined, on the order of to 6000$\%$, for hydrogen anchoring. Applied biases lower than 0.3 V, in conjunction with sulfur anchoring, induce a negative magnetoresistance due to lowering of the anchor-scatterer tunneling barrier. In addition, the diiron-oxo cluster displays nearly perfect spin filtering for parallel alignment of the iron magnetic moments due to energetic proximity, relative to the Fermi level, of its highest occupied molecular orbitals.
View original:
http://arxiv.org/abs/1306.1588
No comments:
Post a Comment