Thursday, January 17, 2013

1301.3769 (M. Tortello et al.)

Huge field-effect surface charge injection and conductance modulation in
metallic thin films by electrochemical gating
   [PDF]

M. Tortello, A. Sola, Kanudha Sharda, F. Paolucci, J. R. Nair, C. Gerbaldi, D. Daghero, R. S. Gonnelli
The field-effect technique, popular thanks to its application in common field-effect transistors, is here applied to metallic thin films by using as a dielectric a novel polymer electrolyte solution. The maximum injected surface charge, determined by a suitable modification of a classic method of electrochemistry called double-step chronocoulometry, reached some units in 10^15 charges/cm^2. At room temperature, relative variations of resistance up to 8%, 1.9% and 1.6% were observed in the case of gold, silver and copper, respectively and, if the films are thick enough (> 25 nm), results can be nicely explained within a free-electron model with parallel resistive channels. The huge charge injections achieved make this particular field-effect technique very promising for a vast variety of materials such as unconventional superconductors, graphene and 2D-like materials.
View original: http://arxiv.org/abs/1301.3769

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